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By K. B. Yatsimirskii

In fresh years many examine employees have became their consciousness to the quantitative characterization of complicated compounds and reactions of complex-formation in resolution. Instability constants represent quantitatively the equili­ bria in ideas of advanced compounds and are largely utilized by chemists of widely-varying specialities, in analytical chemistry, electrochemistry, the know-how of non-ferrous and infrequent metals, etc., for calculations of varied types. regardless of the wealth of numerical info, no kind of complete coliection of instability constants of complicated compounds has been made previously. many of the person collections of knowledge are faraway from whole and normally overlook references to the resource fabrics. in addition, the current kingdom of the chemistry of advanced compounds so much urgently calls for the entire systematization of information on instability constants and an extension of labor during this box which might reap the benefits of the newest physico-chemical equipment. the current paintings includes instability constants for 1,381 advanced compounds. we've got thought of it handy to preface the precis of the instability constants with an introductory element of a normal theoretical personality. This part bargains with tools for the calculation of instability constants from experimental info, the impact of exterior stipulations, corresponding to temperature and ionic power, at the balance of com­ plexes, and the imperative elements opting for the soundness of advanced compounds in aqueous answer. (vii) PREFACE In compiling the precis now we have used the unique litera­ ture and abstracts for the main half as much as 1954, and a few paintings released in 1955-1956.

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Instability Constants of Complex Compounds

In recent times many examine staff have became their realization to the quantitative characterization of complicated compounds and reactions of complex-formation in answer. Instability constants represent quantitatively the equili­ bria in suggestions of complicated compounds and are generally utilized by chemists of widely-varying specialities, in analytical chemistry, electrochemistry, the know-how of non-ferrous and infrequent metals, and so on.

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Am. Chem. , li, 5321 (1951). 24. D. N. HUME, D. D. DeFORD and G. C. , li, 5323 (1951). 25. J. BJERRUM, Metal Ammine Formation in Aqueous Solutions, Copenhagen (1941). 26. K. B. YATSn~IRSKII, Zh. anal. , 10, 339 (1955). 27. K. W. SYKES, H. J. FUDGE, J. Chem. , 124 (1952). 28. R. P. BELL and J. E. , 362 (1949). 29. K. B. YATSn~IRSKII, Zavod. , 21, 1410 (1955). 30. C. M. COOK and F. A. LONG, J. Am. Chem. , li, 4119 (1951). 3l. A. A. GRINBERG and L. E. NIKOL'SKAYA, Zh. prikl. , 22, 542 (1949). 32. A.

W. SYKES, H. J. FUDGE, J. Chem. , 124 (1952). 28. R. P. BELL and J. E. , 362 (1949). 29. K. B. YATSn~IRSKII, Zavod. , 21, 1410 (1955). 30. C. M. COOK and F. A. LONG, J. Am. Chem. , li, 4119 (1951). 3l. A. A. GRINBERG and L. E. NIKOL'SKAYA, Zh. prikl. , 22, 542 (1949). 32. A. K. BABKO and K. E. KLEINER, Zh. obshch. , li, 1259 (1947). 33. A. K. BABKO and T. N. , 18, 1617 (1948). 34. A. B. , J. ~iol. , 107, 351 (1934). 35. C. M. COOK and F. A. LONG, Cited in J. ys. 22" 25 (1952). 36. s. S. JONES and F.

Graphical determination of P, The approximate values of the stability constants can be used to carry out a more precise calculation of the equilibrium concentrations. Continuing the derivation on page 20 we substitute in equation (II. 0. ~~----~--~~~--~--~----~-~ . 0 Thiocyanate concentration, mole/I. Fig. 3. Graphical determination of ~. 75·10-2;;~. IOe) When the equation obtained is solved using Horner's method or the method of substitutions, values are obtained for the equilibrium concentrations.

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