By Peter I. Dalko
A much-needed evaluation reflecting the advancements over the last 5 years, this can be the main accomplished instruction manual on organocatalysis. As such, all correct catalyst structures are mentioned intimately, in addition to key options, response kinds, and critical purposes in overall synthesis. the 1st volumes hide catalyst constructions and fundamental activation kinds. those chapters let readers to familiarize themselves with the fairly advanced interactions that make organocatalytic reactions selective; to achieve an perception into the most productive catalyst varieties; and to appreciate the significance of actual parameters that impression reactivity and selectivity. quantity 3 is established round response varieties, i.e. nucleophile additions to C=X and C=C bonds; Friedel-Crafts reactions, organocatalytic sigmatropic reactions, regioselective reactions and desymmetrization techniques, ring-forming reactions, multicomponent (domino) reactions, multicatalyst structures and the applying of organocatalytic reactions in multistep synthesis are mentioned. An appendix recollecting catalyst constructions with the sufficient cross-references to the corresponding chapters rounds off the book.
With its contributions written via pioneers of the organocatalysis box, this booklet offers non-specialists with an advent to the subject in addition to serving as a necessary resource for researchers in academia and looking for an updated and complete evaluate of this promising quarter of man-made natural chemistry
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Extra resources for Comprehensive Enantioselective Organocatalysis: Catalysts, Reactions, and Applications
The aim of this multiauthor book was to recollect efficient organocatalytic reactions around clear principles that meet actual standards in asymmetric synthesis. Chapters were written in a concise way, and this condensed treatment is supported by more than 1400 schemes and figures, providing condensed visual information at a glance. The book was kept updated with the literature until spring/summer 2012. Considering the historically broad interest in the field, the book wishes to address a large audience: academic or industrial researchers, students, and teachers who are interested in synthetic organic chemistry at an advanced level.
Herrera CSIC-Universidad de Zaragoza Instituto de Síntesis Química y Catálisis Homogénea (ISQCH) Departamento de Química Orgánica Laboratorio de Síntesis Asimétrica Plz de San Francisco s/n 50009 Zaragoza Spain Karl Anker Jørgensen Aarhus University Department of Chemistry Center for Catalysis Langelandsgade 140 8000 Aarhus Denmark Henk Hiemstra University of Amsterdam Van ‘t Hoff Institute for Molecular Sciences Science Park 904 1098 XH Amsterdam The Netherlands Hao Jiang Aarhus University Department of Chemistry Center for Catalysis Langelandsgade 140 8000 Aarhus Denmark Pavel Kocˇovský University of Glasgow Department of Chemistry University Avenue Glasgow G12 8QQ UK List of Contributors XXXV Hiyoshizo Kotsuki Kochi University Faculty of Science Laboratory of Natural Products Chemistry Akebono-cho Kochi 780-8520 Japan Carsten Kramer Karlsruher Institut für Technologie (KIT) Institut für Organische Chemie Fritz-Haber-Weg 6 76131 Karlsruhe Germany Tor Erik Kristensen University of Oslo Department of Chemistry P.
XXVIII Foreword territories, which in turn are valuable windows of opportunities for further breakthrough research. It appears to be in this spirit that the present book is edited. I think these efforts are highly laudable and the editor has tried very hard to organize organocatalysis in a rational manner. He also has put a lot of effort on identifying the leading people in the field and on recruiting them as authors. What a massive and impressive task! Efforts such as the present one are of great value in encouraging further studies from the next generation of chemists.