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By Abello T.P.

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The chemical potential of electrons µθ in dielectric material can be represented as µθ = EF – EC, where EC is the bottom level of the conductivity zone. 9 Nanoscaled SEM images of (a) YSZ electrolyte and (b) Pt electrode. , Electron model of solid oxygen-ionic electrolytes used in gas sensors, Int. J. Applied Ceramic Techn. 3 (2006) 401–411. 10 TEM image in the vicinity of interface between YSZ and the NiO-SE sintered at 1400°C. , Electron model of solid oxygen-ionic electrolytes used in gas sensors, Int.

They are adsorption–desorption of electrochemically active gaseous components on gas-electrolyte (GE) and gas-metal (GM) interfaces, ionization reaction (with electron transfer) on the metal-electrolyte (ME) and gas-electrolyte interfaces, and mass-transfer processes on all boundaries of three phases (gas-metal, gas-electrolyte, and metal-electrolyte). Furthermore, mass transfer of electrons and holes on the surface electrolyte layer may also occur. It is evident that the quantity of the current in the stationary state is equal to the quantity of the nonmetal component adsorbing on the gas-metal and gas-electrolyte surfaces as a result of ionization of this component on the ME and GE surfaces.

Part 1: Basic properties and terms, Adv. Appl. Ceramics 104 (2005) 147–153. fm Page 40 Wednesday, June 27, 2007 11:41 AM 40 Electrochemistry of Zirconia Gas Sensors 6. , Phase equilibria and ordering in the system ZrO2–Y2O3, J. Amer. Ceram. Soc. 61 (1978) 17–21. 7. P. , Defect structure of yttria-stabilized zirconia and its influence on the ionic conductivity at elevated temperatures, Physical Review B 59 (1999) 14202–14220. 8. Kopp, A. , in Science and technology of zirconia, Eds. S. J. J. Hannik, Lancaster, PA, Technomic Publishing, 1993, 567–575.

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